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|Section2= |Section3= }} Sodium cyclopentadienide is an organosodium compound with the formula C5H5Na. The compound is often abbreviated as NaCp, where Cp− is the cyclopentadienide anion. Sodium cyclopentadienide is a colorless solid, although samples often are pink owing to traces of oxidized impurities.〔 ==Preparation== Sodium cyclopentadienide is commercially available as a solution in THF. It is prepared by treating cyclopentadiene with sodium: :2 Na + 2 C5H6 → 2 NaC5H5 + H2 Commonly, the conversion is conducted by heating a suspension of molten sodium in dicyclopentadiene.〔Tarun K. Panda, Michael T. Gamer, Peter W. Roesky "An Improved Synthesis of Sodium and Potassium Cyclopentadienide" Organometallics, 2003, 22, 877–878.〕 In former times, the sodium was commonly provided in the form of "sodium wire" or "sodium sand", a fine dispersion of sodium prepared by melting sodium in refluxing xylene and rapidly stirring. Sodium hydride is a convenient base: :NaH + C5H6 → NaC5H5 + H2 In early work, Grignard reagents were used as bases. With a p''K''a of 15, cyclopentadiene can be deprotonated by many reagents. The nature of NaCp depends strongly its medium and for the purposes of planning syntheses, the reagent is often represented as a salt Na+C5H5−. Crystalline solvent-free NaCp, which is rarely encountered, is a "polydecker" sandwich complex, consisting of an infinite chain of alternating Na+ centers sandwiched between μ-η5:η5-C5H5 ligands. As a solution in donor solvents, NaCp is highly solvated, especially at the alkali metal as suggested by the isolability of the adduct Na(tmeda)Cp. 抄文引用元・出典: フリー百科事典『 ウィキペディア（Wikipedia）』 ■ウィキペディアで「Sodium cyclopentadienide」の詳細全文を読む スポンサード リンク
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